Kinetic Theory

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New answer posted•a year ago
S
a year ago

Degree of freedom, f = 8

∴CV=82R=4R  and   CP=4R+R=5R

So, H = ΔU+W

at constant pressure, W = PΔv

150 = nRΔT

So,  H=nCVΔT=n5RΔT=5 (nRΔT)

= 5 × 150

= 750 J

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New answer posted•a year ago
New answer posted•a year ago
S
a year ago

x ¯ (mean free path) = 1 2 π d 2 n v  

n v = n N A v , n → No. of moles in volume v NA ® Avogadro’s Number

n v = P R T

x ¯ ∝ v ∝ 1 ρ ( d e n s i t y &     x ¯ α T     a t   c o n s t a n t   P )

ρ ↑ ⇔ x ¯ ↓     | x ¯ ↑ ⇔ T ↑                           

The motion of the gas molecules freezes at 0K not 0° C

Average kinetic Energy per molecule

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New answer posted•a year ago
S
a year ago

This is a multiple choice answer as classified in NCERT Exemplar

When the gas is compressed adiabatically, the total work done on the gas increases its internal energy which in turn increases the KE of the gas molecule and hence, the collisions between molecules also increases.

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New answer posted•a year ago
S
a year ago

This is a multiple choice answer as classified in NCERT Exemplar

(a), (c) pV=nRT

(a) when pressure p =constant

volume is directly proportional to temperature

(b) when T= constant

from PV =constant

so the graph is rectangular hyperbola

(c) when V =constant

from pressure is directly proportional to temper

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New answer posted•a year ago
S
a year ago

This is a multiple choice answer as classified in NCERT Exemplar

(a), (d) The total energy associated with the molecule is

E= 1 2 m v x 2 + 1 2 m v y 2 + 1 2 m v z 2 + 1 2 I x w x 2 + 1 2 I y w y 2

The number of independent terms in the above expressions is 5. So we can predict velocities of molecule by maxwell’s distribution, hence the above expression obeys maxwell ‘s

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New answer posted•a year ago
New answer posted•a year ago
S
a year ago

This is a multiple choice answer as classified in NCERT Exemplar

(b), (d) due to the presence of external positive charge on face ABCD. The usual expression for pressure on the basis of kinetic energy will not be valid as ions would also experience electrostatic force. So presence of positive charge

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New answer posted•a year ago
S
a year ago

This is a multiple choice answer as classified in NCERT Exemplar

(d) pV=nRT

So n= PV/RT

As number moles are fixed

P 1 V 1 R T 1 = P 1 V 1 R T 1

P2=p1V1 (T2/V2T1)

= pV (1.1T)1.05V (T)

= P × 1.1 1.05 ≈ 1.05 P

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New answer posted•a year ago