Kinetic Theory
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13.9 At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of a helium gas atom at – 20 °C ? (atomic mass of Ar = 39.9 u, of He = 4.0 u).
13.9 At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of a helium gas atom at – 20 °C ? (atomic mass of Ar = 39.9 u, of He = 4.0 u).
13.9 Temperature of the helium atom, = – 20 °C = 253 K and temperature of argon atom be =
Atomic mass of helium, = 4.0 u
Atomic mass of Argon, = 39.9 u
Let be the rms speed of Argon and be the rms speed of Helium
From the relation of 
13.8 Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrms the largest?
13.8 Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrms the largest?
13.8 (a) According to Avogadro's law, the three vessels will contain an equal number of the respective molecules. This number is equal to Avogadro's number, N = 6.023
(b) The root mean square speed ( of a gas of mass m and temperature T is given by the relation . Where k
13.7 Estimate the average thermal energy of a helium atom at (i) room temperature (27 °C), (ii) the temperature on the surface of the Sun (6000 K), (iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
13.7 Estimate the average thermal energy of a helium atom at (i) room temperature (27 °C), (ii) the temperature on the surface of the Sun (6000 K), (iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
13.7 (i) At room temperature, T = 27 = 300 K
is Boltzmann constant = 1.38
Average thermal energy = = = 6.21 J
Hence, the average thermal energy of a helium atom at room temperature is 6.21 J
(ii) On the surface of the Sun, T = 6000
13.6 Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 at a temperature of 27 °C and 1 atm pressure.
13.6 Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 at a temperature of 27 °C and 1 atm pressure.
13.6 Volume of the room, V = 25.0
Temperature of the room, T = 27 = 300 K
Pressure of the room, P = 1 atm = 1 1.013 Pa
The ideal gas equation relating to pressure (P), volume (V) and absolute temperature (T) can be written as
PV = NT, where &nb
13.5 An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
13.5 An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
13.5 Volume of the air bubble = 1.0 = 1
Height achieved by bubble, d = 40 m
Temperature at a depth of 40 m, = 12 = 285 K
Temperature at the surface of the lake, = 35 = 308 K
The pressure at the surface of the lake,&
13.4 An oxygen cylinder of volume 30 litres has an initial gauge pressure of 15 atm and a temperature of 27 °C. After some oxygen is withdrawn from the cylinder, the gauge pressure drops to 11 atm and its temperature drops to 17 °C. Estimate the mass of oxygen taken out of the cylinder (R = 8.31 J mol–1 K–1, molecular mass of O2 = 32 u).
13.4 An oxygen cylinder of volume 30 litres has an initial gauge pressure of 15 atm and a temperature of 27 °C. After some oxygen is withdrawn from the cylinder, the gauge pressure drops to 11 atm and its temperature drops to 17 °C. Estimate the mass of oxygen taken out of the cylinder (R = 8.31 J mol–1 K–1, molecular mass of O2 = 32 u).
13.4 Volume of oxygen, = 30 litres = 30
Gauge pressure, = 15 atm = 15 Pa
Temperature, = 27 = 300 K
Universal gas constant, R = 8.314 J/mole/K
Let the initial number of moles of oxygen gas cylinder be
From the gas equation, we get&nbs
13.3 Figure 13.8 shows plot of PV/T versus P for 1.00×10–3 kg of oxygen gas at two different temperatures.

(a) What does the dotted plot signify?
(b) Which is true: T1 > T2 or T1 < T2?
(c) What is the value of PV/T where the curves meet on the y-axis?
(d) If we obtained similar plots for 1.00×10–3 kg of hydrogen, would we get the same value of PV/T at the point where the curves meet on the y-axis? If not, what mass of hydrogen
Yields the same value of PV/T (for low pressure high temperature region of the plot) ? (Molecular mass of H2 = 2.02 u, of O2 = 32.0 u, R = 8.31 J mo1–1 K–1.)
13.3 Figure 13.8 shows plot of PV/T versus P for 1.00×10–3 kg of oxygen gas at two different temperatures.

(a) What does the dotted plot signify?
(b) Which is true: T1 > T2 or T1 < T2?
(c) What is the value of PV/T where the curves meet on the y-axis?
(d) If we obtained similar plots for 1.00×10–3 kg of hydrogen, would we get the same value of PV/T at the point where the curves meet on the y-axis? If not, what mass of hydrogen
Yields the same value of PV/T (for low pressure high temperature region of the plot) ? (Molecular mass of H2 = 2.02 u, of O2 = 32.0 u, R = 8.31 J mo1–1 K–1.)
13.3 (a) The dotted plot in the graph signifies the ideal behaviour of the gas, i.e. = R, (where is the number of moles and R is the universal gas constant) is a constant quantity. It is not dependent on the pressure of the gas. The curve of the gas at temperatu
13.2 Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
13.2 Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
13.2 The ideal gas equation relating to pressure (P), volume (V) and absolute temperature (T) is given by the relation
PV = nRT, where
R is the universal gas constant = 8.314 J /mol/K
N = number of moles = 1 (given)
T = standard temperature = 273 K
P = standard p
13.1 Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3 Å.
13.1 Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3 Å.
13.1 Diameter of the oxygen molecule, d = 3Å
Radius, r = = 1.5 Å = 1.5 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22.4 lit = 22400
Molecular volume of oxygen gas, V = N,
where N = Avogadro's number = 6.023 molecules/mole
Therefore, V =&nb