Aldehydes, Ketones and Carboxylic Acids

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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A
alok kumar singh

Contributor-Level 10

Kindly go through the solution 

 

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A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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P
Payal Gupta

Contributor-Level 10

Acidic order

Simple concept of conjugate base stability

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Payal Gupta

Contributor-Level 10

Conversion form

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Payal Gupta

Contributor-Level 10

(1) 4 mol of =4A atoms

(2) 4 u of =4u4u=1 atom

(3) 4 g of Helium =44 mole =1 mole =NA He atom

(4) 2.2710982 of He at STP =2.27122.710982 mole

=0.1

=0.1A

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alok kumar singh

Contributor-Level 10

Nucleophilic addition of sodium hydrogen sulphite to aldehyde or ketone is a;

N a H S O 3 ? N a + + H S O 3 ?                

 

So; nucleopilic addition of sodium hydrogen sulphite to an aldehyde or a ketone involves proton transfer to form a stable ion.

Addition of hydrogen cyanide;

Final product is cyanohydrin.

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Payal Gupta

Contributor-Level 10

Kindly consider the below image

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alok kumar singh

Contributor-Level 10

Reaction of acetone and semicarbazide

 

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alok kumar singh

Contributor-Level 10

All structure can produce -CHO functional group which gives +ve test of Tollen's reagent except structure (II), because if forms ketonic group after tautomerisation

 

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