Amines
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New answer posted
a month agoContributor-Level 10
Kjeldahl's method does not work for heterocyclic and azo compounds.
New answer posted
a month agoContributor-Level 10
Aliphatic diazonium salts are not stable. Aromatic diazonium salts exist at low temp of 0 – 4°C.
New answer posted
a month agoContributor-Level 9
R-CONH? + Br? + 4NaOH → R-NH? + 2NaBr + Na? CO? + 2H? O
This reaction is the Hoffmann bromamide degradation, in which an amide is converted to a 1° amine.
New answer posted
a month agoContributor-Level 10
In diacetamide (CH? CO)? NH), the lone pair of electrons on the nitrogen atom is delocalized through resonance with both adjacent carbonyl groups. This extensive resonance greatly decreases the electron density on the nitrogen atom.
New answer posted
a month agoContributor-Level 9
Only 1° amine react with benzene sulphonyl chloride to give a compound which is soluble in alkali
New answer posted
a month agoContributor-Level 10
In the ammonolysis reaction, HCl is produced as a byproduct. To neutralize this acidic impurity, the mixture is treated with NaOH.
New answer posted
a month agoContributor-Level 9
In Hoffmann bromamide reaction, hypobromite ion react with amide and in this reaction carbonyl group is lost as CO? ²? in form of Na? CO?
New answer posted
a month agoContributor-Level 10
In the ammonolysis process, bond cleavage is carried out in the presence of NH? When a halide compound is treated with NH? , the halide ion (X? ) is substituted by an amino group (NH? ) in a nucleophilic substitution reaction.
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