Amines

$\frac{1.86}{93}=\frac{w}{135}$

W = 2.70 g

Mass produced actual = 2.70 $*\frac{90}{100}=2.43=243*10^{-2}g$

Gabriel phthalimide synthesis is used for 1° Aliphatic /alicyclic amine

1° Amine

CH₃ – CH₂ – NH₂

Kindly consider the following figure

Stable carbocation formation is the important factor.

Primary amine, whether aliphatic or aromatic when warmed with CHCl₃, alcoholic (KOH) it forms isocyanide

Mass of empty cylinder = 14.8 kg

Mass of cylinder when full = 29 kg

Mass of gas in cylinder when filled; W₁ = 29 – 14.8 = 14.2 kg

Mass of gas in cylinder after using, W₂ = 23 – 14.8 = 8.2 kg

Initial pressure ; P₁ = 3.47 atm

Final pressure ; P₂ =?

Using

  $PV=\frac{W}{M}RT$

$P_{1}V=\frac{W_1}{M}RT..........\left(I\right)$              

$P_{2}V=\frac{W_2}{M}RT...........\left(II\right)$                 

$\frac{P_1}{P_2}=\frac{W_1}{W_2}$                

$\frac{3.47}{P_2}=\frac{14.2}{8.2}$                

P₂ = atm

$C_2{H}_{7}N+\left(2x+\frac{y}{2}\right)CuO\to xC{O}_2+\frac{y}{2}{H}_{2}O+\frac{Z}{2}{N}_2+\left(2x+\frac{y}{2}\right)Cu$

$C_2{H}_7{N}_1+\left(2*2+\frac{7}{2}\right)CuO\to 2C{O}_2+\frac{7}{2}{H}_{2}O+\frac{1}{2}{N}_2+\left(2*2+\frac{7}{2}\right)Cu$              

$\therefore y=7$              

Ans. = 7

Dumas method,

Moles of N in N, N-dimethylaminopentane (C₇H₁₇N)

$=\frac{57.5}{115}=0.5mole$

$C_7{H}_{17}N+\frac{45}{2}CuO\to 7C{O}_2+\frac{17}{2}{H}_{2}O+\frac{1}{2}{N}_2+\frac{45}{2}Cu$

$\frac{n_{CuO}}{\left(\frac{45}{2}\right)}=\frac{n_{c_7{H}_{17}N}}{1}$

$n_{CuO}=\left(\frac{45}{2}\right)*0.5mol$

= 11.25 mol

= 1125 * 10^-2 mol

Ans. = 1125