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New answer posted

6 months ago

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V
Vishal Baghel

Contributor-Level 10

Using the equation Kp = Kc (RT)ng

(i) From the given equation, Δng = 3 – 2 = 1,

R = 0.0821 L atm K-1 mol-1

T = 500 K, Kp= 1.8 * 10–2

Thus, Kc = Kp / (RT)ng= (1.8 x 10-2) / (0.0821 L atm K-1 mol-1 x 500 K)

4.4 x 10-4 mol L-1

 

(ii) From the given equation, Δng =1,

R = 0.0821 L atm K-1 mol-1

T = 1073 K, Kp= 167 atm

Thus, Kc = Kp / (RT)ng= (167 atm) / (0.0821 L atm K-1 mol-1 x 1073 K)

= 1.9 mol L-1

New answer posted

6 months ago

0 Follower 9 Views

V
Vishal Baghel

Contributor-Level 10

(i) The expression for the equilibrium constant is Kc= [NO]2 [Cl2] / [NOCl]2.

(ii) The expression for the equilibrium constant is Kc= [NO2]4 [O2] / [ (2Cu (NO3)2]2  = [NO2]4 [O2].

(iii) The expression for the equilibrium constant is Kc= [CH3COOH] [C2H5OH] / [CH3COOC2H5].

(iv) The expression for the equilibrium constant is Kc= 1 / [Fe3+] [OH]3.

(v) The expression for the equilibrium constant is Kc= [IF5]2 / [F2]5.

New answer posted

6 months ago

0 Follower 1 View

V
Vishal Baghel

Contributor-Level 10

According to the given condition,

Total pressure of equilibrium mixture = 105 Pa

Partial pressure of iodine atoms (I), PI = 40 % of 105 Pa

= 0.4 x 105 Pa

Partial pressure of iodine molecules (I2), PI2 = 60 % of 105 Pa

= 0.6 x 105 Pa

Kp for the equilibrium = (PI)2/ PI2 = (0.4 x 105 Pa)2 / (0.6 x 105 Pa)

= 2.67 x 104 Pa

New answer posted

6 months ago

0 Follower 1 View

V
Vishal Baghel

Contributor-Level 10

(a) On increasing the volume of the container, the vapour pressure will initially decrease because the same amount of vapours is now distributed over a larger space.

(b) On increasing the volume of the container, the rate of evaporation will increase initially because now more space is available. Since the amount of the vapours per unit volume decrease on increasing the volume, therefore, the rate of condensation will decrease initially.

(c) Finally, equilibrium will be restored when the rates of the forward and backward processes become equal. However, the vapour pressure will remain unchanged because it depends upon the tempera

...more

New answer posted

6 months ago

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P
Payal Gupta

Contributor-Level 10

5.7. Applying PV = nRT

                      We get P = nRT / V

Given:               nCH4 = 3.2 / 16 mol = 0.2 mol

              nCO2 = 4.4 /44 mol = 0.1 mol

So,

PCH4 = (0.2 mol) (0.0821 dm3atm K-1 mol-1) (300 K) / (9 dm3)

        = 0.55 atm

 PCO2= (0.1 mol) (0.0821 dm3atm K-1 mol-1) (300 K) / (9 dm3)

         = 0.27 atm

Ptotal =

...more

New answer posted

6 months ago

0 Follower 2 Views

P
Payal Gupta

Contributor-Level 10

5.6. The chemical equation for the reaction is
                                    2 Al + 2 NaOH + H2O? 2 NaAlO2 + 3H2 
i.e. 2 moles of Al give 3 moles of H2 gas.

Moles of aluminium = 270.15g = 5.56*10?3 moles

Moles of H2 produced= 23*5.56*10?3

           = 8.33*10?3 moles

           Volume of H2 = nRT / P

        &nbs

...more

New answer posted

6 months ago

0 Follower 1 View

P
Payal Gupta

Contributor-Level 10

5.5. Suppose molecular masses of A and B are MA and MB respectively. Then their number of moles will be

nA= 1/MA                                nB = 2/MB

Given: PA = 2 bar        and PA + PB = 3 bar

          => PB = 1bar

Since, PV = nRT

PA= nART and PBV= nBRT

Therefore, (PA / PB) = (nA / nB)= (MB / 2MA)

=> MB / MA = 2 x PA / PB = 2 x 2 /1 = 4

        => MB = 4 MA

New answer posted

6 months ago

0 Follower 1 View

P
Payal Gupta

Contributor-Level 10

Answer: According to ideal gas equation
                        PV = nRT

Or                        P= nRT/V

Replacing n by m/M, we get

                            P M1 x 2 = 28 x 5 (Molecular mass of N2 = 28 g/mol)
or           

...more

New question posted

6 months ago

0 Follower 6 Views

New question posted

6 months ago

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