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Payal Gupta

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15. The reactions are explained as:

MnO2 +  4HCl → MnCl2 +  Cl2 +  2H2O

  (A)                                       (B)

3Cl2 +     2NH3 → NCl3 +  3HCl

(excess)                          (C) 

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Vishal Baghel

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alok kumar singh

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35. Option (i) and (ii)

In the extraction of alumina by Hall-Heroult's process, alumina is mixed with cryolite with the mixture of fluorspar \& fluoride that increases the conductivity of electrical and lowers the melting point of Al2O3 .

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Vishal Baghel

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Payal Gupta

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14. Higher enthalpy of hydration provides extra stability to Cu2+  oxidation state than  +1 oxidation state. 

Enthalpy of hydration is described as the amount of energy released on dilution of one mole of gaseous ions.

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Vishal Baghel

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alok kumar singh

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34. Option (i) and (iv)

Pig iron is the iron obtained from the blast that has many impurities (Mn, P, Si, etc.) and approximately 4% carbon content. When it is re-melted or cast with the help of scrap iron, then it has less carbon content i.e. 3% as compared to pig iron.

The Zr andTi are purified by the help of Arkel Method that contain the following reaction: 

Zr (s) + 2I2   ZrI4 ( g)  Zr Pure  (s) + 2I2

Ti + 2I2  TiI4  Ti + 2I2

Here we obtain Zr and Ti as a pure form of solid when purified using the Arkel method.

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Vishal Baghel

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Payal Gupta

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13. 2Cu2+  +    4I-  → Cu2I2 + I2

When Cu2+  reacts with potassium iodide white precipitate of Cu2I2 is formed.

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Vishal Baghel

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