Ncert Solutions Chemistry Class 11th

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Vishal Baghel

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The catenation depends on the strength of the element-element bond. As we move down the group 14, the element-element bond energies decrease rapidly, viz. C–C (355 kJ mol–1), Si–Si (222 kJ mol–1), Ge–Ge (167 kJ mol–1) and Sn–Sn (155 kJ mol–1), so the tendency for catenation decreases in the order C > Si > Ge > Sn.

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Vishal Baghel

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Carbon atoms have the tendency to linkwith one another through covalent bonds to form chains and rings. This property is calledcatenation. This is because C—C bonds are very strong.

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Vishal Baghel

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Boron shows anomalous behaviour due to small atomic size, high electronegativity, high ionization energy and absence of d-orbital of B

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Vishal Baghel

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  (b) SiO44- is the basic unit of all silicates.

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Vishal Baghel

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(a) Producer gas is a mixture of CO and N2 in the ratio of 2 :1

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Vishal Baghel

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(d) CO2 is regarded as anhydride of carbonic acid.

H2CO3 ————> H2O + CO2

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Vishal Baghel

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(d) is an incorrect statement because non-metal oxides are acidic or neutral whereas metal oxides are basic in nature.

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Vishal Baghel

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(c) Boron halides are Lewis acids and can accept a pair of electrons from amines to form addition product.

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Vishal Baghel

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(d) Heavier elementsdo not form pπ– pπ bonds because their atomicorbitals are too large and diffuse to haveeffective overlapping.

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