Ncert Solutions Chemistry Class 11th

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Payal Gupta

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9.36.  (i) Hydrogen economy: The basic principle of hydrogen economy is the storage and transportation of energy in the form of liquid or gaseous dihydrogen.

(ii) Hydrogenation: Hydrogenation means addition of hydrogen across double and triple bonds in presence of catalyst to form saturated compounds.

(iii) Syngas: The mixture of CO and H2 are called synthesis gas or 'syngas'. It can be produced by the reaction of steam on hydrocarbon or coke at high temperature in the presence of nickel catalyst

(iv) Water-gas shift reaction: The amount of hydrogen in the syngas can be increased by the action of CO of syngas m

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Payal Gupta

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9.35. Bleaching action of H2O2 is due to the oxidation of colouring matter by nascent oxygen.
H2O2→ H2O + O

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Payal Gupta

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9.34. KCl is a salt of strong acid HCl and strong base KOH. Such salts are neutral in nature and do not undergo hydrolysis. In neutral water, acidic water, and alkaline water, KCl dissociates as
      Water

KCl → ?K++Cl
AlCl3? is a salt of strong acid HCl and weak base Al(OH)3?.

(i) In normal water, it is hydrolyzed.
AlCl3?+3H2?O→Al(OH)3?+3H++3Cl

(ii) In acidic water, H+ ions react with Al(OH)3?  (obtained from the hydrolysis of AlCl3?) forming water and Al3+ ions.  Hence it exists as Al3++Cl−
AlCl3? + acidifiedwater? → Al++3Cl

(iii) In alkaline wa

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Payal Gupta

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9.33. Atomic number 15 is of phosphorus. The hydride is PH3 and its nature is covalent. Atomic number = 19 is of potassium. The hydride is KH and it is ionic in nature. Atomic number = 23 is of vanadium. The hydride is VH. It is interstitial or metallic. Atomic number =44 is of ruthenium, its hydride is interstitial or metallic.

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Payal Gupta

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9.32. Saline hydrides (i.e. CaH2 NaH etc.) react with water and form the corresponding metal hydroxide with the liberation of Hgas. Thus, these hydrides can be used to remove traces of water from the organic compounds.

NaH (s) + H2O (l) → NaOH (aq) + H2 (g)

CaH2 (s) + 2H2O (l) → Ca (OH)2 (aq) + H2 (g)

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Payal Gupta

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9.31. (H+ and OH ions) of water molecule react with a compound to form products. For example:

NaH+H2O → NaOH+H2

Hydration is defined as the addition of one or more water molecules to ions or molecules to form hydrated compounds. For example:

CuSO4+5H2O → CuSO4.5H2O

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Payal Gupta

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9.30. No, D2O is injurious to human beings, plants and animals.

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Payal Gupta

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9.29. Water is highly polar in nature. That is why it has high dielectric constant and high dipole moment. Because of these properties, water is a universal solvent.

Water is good solvent for ionic compounds but poor solvent for covalent compounds. It can hydrolyse ionic compounds.

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Payal Gupta

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9.28.  (i) Major part of all living system is made of water.

(ii) It constitutes about 65 – 70% of body weights of animals and plants.

(iii) Some properties of water like high specific heat, thermal conductivity, surface tension, high polarity allow water to play a major role in biosphere.

(iv) Because of high heat of vaporisation it is responsible to regulate temperature of living beings.

(v) It is an excellent fluid for the transportation of minerals and nutrients in plants.

(vi) It is also required for photosynthesis in plants.

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Payal Gupta

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9.27. No, demineralised or distilled water is not fit for drinking purposes. It can be made useful by adding required amount of ions which are useful for our body.

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