Physics Thermodynamics
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In the reported figure, there is a cyclic process ABCDA on a sample of 1mol of a diatomic gas. The temperature of the gas during the process A→B and C→D are T? and T? (T? > T?) respectively. Choose the correct option out of the following for work done if processes BC and DA are adiabatic.
In the reported figure, there is a cyclic process ABCDA on a sample of 1mol of a diatomic gas. The temperature of the gas during the process A→B and C→D are T? and T? (T? > T?) respectively. Choose the correct option out of the following for work done if processes BC and DA are adiabatic.
A→B & D→C (isothermal process)
So, TA = TB & TD = TC. Now B→C & D→A (adiabatic process)
|WBC| = nR/ (γ-1) (TB - TC)
|WAD| = nR/ (γ-1) (TA - TD) = nR/ (γ-1) (TB - TC)
∴ |WBC| = |WAD|
For a gas C? - C? = R in a state P and C? - C? = 1.10 R in a state Q, T? and T? are the temperatures in two different states P and Q respectively. Then
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For a gas C? - C? = R in a state P and C? - C? = 1.10 R in a state Q, T? and T? are the temperatures in two different states P and Q respectively. Then
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C? = dQ/ndT = (dU + pdV)/ndT
= C? + (pdV/ndT)
C? - C? = pdV/ndT = R - For ideal Gas [Box: PV = nRT, pdV = nRdT]
C? - C? = 1.1R - For Non – Idea gas (for Real gas)
And Real gas behaves as ideal gas at high temperature & low pressure.
∴ T_B > T_A
A monoatomic ideal gas, initially at temperature T?, is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature T? by releasing the piston suddenly. If ? and ? are the lengths of the gas column, before and after the expansion respectively, then the value of T?/T? will be :
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A monoatomic ideal gas, initially at temperature T?, is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature T? by releasing the piston suddenly. If ? and ? are the lengths of the gas column, before and after the expansion respectively, then the value of T?/T? will be :
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For adiabatic process
T? V? ¹ = T? V? ¹
⇒ T? (Al? )? ¹ = T? (Al? )? ¹
T? /T? = (l? /l? )? ¹ = (l? /l? )? /³? ¹ = (l? /l? )?
A heat engine has an efficiency of 1/6. When the temperature of sink is reduced by 62°C, its efficiency get doubled. The temperature of the source is :
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A heat engine has an efficiency of 1/6. When the temperature of sink is reduced by 62°C, its efficiency get doubled. The temperature of the source is :
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η = 1 - T? /T?
1/6 = 1 - T? /T? (i)
2η = 1/3 = 1 - (T? -62)/T? (ii)
By (i) and (ii)
(T? /T? ) = 5/6
1/3 = 1 - (T? /T? ) + 62/T? = 1 - 5/6 + 62/T?
1/3 = 1/6 + 62/T?
1/6 = 62/T?
T? = 62 × 6 = 372K = 99°C
n mole of perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A->B : Isothermal expansion at temperature T so that the volume is doubled from V1 to V2 and Pressure changes from P1 to P2.
B->C : Isobaric compression at pressure P2 to initial volume V1.
C->A : Isobaric change leading to change of pressure from P2 to P1.
Total work done in the complete cycle ABCA is:
n mole of perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A->B : Isothermal expansion at temperature T so that the volume is doubled from V1 to V2 and Pressure changes from P1 to P2.
B->C : Isobaric compression at pressure P2 to initial volume V1.
C->A : Isobaric change leading to change of pressure from P2 to P1.
Total work done in the complete cycle ABCA is:
[At B, 2P2 V1 = nRT]
Match List I with List II.
List I List II
(a) Isothermal (i) Pressure constant
(b) Isochoric (ii) Temperature constant
(c) Adiabatic (iii) Volume constant
(d) Isobaric (iv) Heat content is constant
Choose the correct answer from the options given below:
Match List I with List II.
List I List II
(a) Isothermal (i) Pressure constant
(b) Isochoric (ii) Temperature constant
(c) Adiabatic (iii) Volume constant
(d) Isobaric (iv) Heat content is constant
Choose the correct answer from the options given below:
In isothermal process, temperature is constant.
In isochoric process, volume is constant.
In adiabatic process, there is no exchange of heat.
In isobaric process, pressure is constant
1 mole of rigid diatomic gas performs a work of <!-- [if gte mso 9]><xml>
</xml><![endif]--> when heat Q is supplied to it. The molar heat capacity of the gas during this transformation is <!-- [if gte mso 9]><xml>
</xml><![endif]--> The value of x is………
[R = universal gas constant]
1 mole of rigid diatomic gas performs a work of <!-- [if gte mso 9]><xml>
[R = universal gas constant]
The volume V of a given mass of monoatomic gas changes with temperature T according to the relation <!-- [if gte mso 9]><xml>
</xml><![endif]--> The work done when temperature changes by 90 K will be xR. The value of x is…….
[R = universal gas constant]
The volume V of a given mass of monoatomic gas changes with temperature T according to the relation <!-- [if gte mso 9]><xml>
[R = universal gas constant]
The internal energy (U), pressure (P) and volume (V) of an ideal gas are related as U = 3PV + 4. The gas is:
The internal energy (U), pressure (P) and volume (V) of an ideal gas are related as U = 3PV + 4. The gas is:
A container is divided into two chambers by a partition. The volume of first chamber is 4.5 litre and second chamber is 5.5 litre. The first chamber contain 3.0 moles of gas at pressure 2.0 atm and second chamber contains 4.0 moles of gas at pressure 3.0 atm. After the partition is removed and the mixture attains equilibrium, then, the common equilibrium pressure existing in the mixture is x × 10-1 atm. Value of x is----------.
A container is divided into two chambers by a partition. The volume of first chamber is 4.5 litre and second chamber is 5.5 litre. The first chamber contain 3.0 moles of gas at pressure 2.0 atm and second chamber contains 4.0 moles of gas at pressure 3.0 atm. After the partition is removed and the mixture attains equilibrium, then, the common equilibrium pressure existing in the mixture is x × 10-1 atm. Value of x is----------.

