Equilibrium
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Given below are two statements : one is labeled as Assertion A and the other is labeled as Reason R.
Assertion A: Phenolphthalein is pH dependent indicator, remains colourless in acidic solution and gives pink colour in basic medium.
Reason R: Phenolphthalein is a weak acid. It doesn’t dissociate in basic medium.
In the light of the above statements, choose the most appropriate answer from the options given below.
Given below are two statements : one is labeled as Assertion A and the other is labeled as Reason R.
Assertion A: Phenolphthalein is pH dependent indicator, remains colourless in acidic solution and gives pink colour in basic medium.
Reason R: Phenolphthalein is a weak acid. It doesn’t dissociate in basic medium.
In the light of the above statements, choose the most appropriate answer from the options given below.
Phenolphtalein is a pH dependant indicator. It is a weak acid which is colourless in acidic medium but gives pink colour in basic medium. The pink colour is due to its conjugate form. Phenolphthalein dissociates in basic medium. Therefore, assertion is true but reason is false.
For the equilibrium , the variation of the rate of the forward (a) and reverse (B) reaction with time is given by:
For the equilibrium , the variation of the rate of the forward (a) and reverse (B) reaction with time is given by:
At equilibrium rate of forward and backward reaction becomes equal.
At 600K, 2 mol of NO are mixed with 1 mol of O2.
2NO(g) + O2(g) 2NO2(g)
The reaction occurring as above comes to equilibrium under a total pressure of 1 atm. Analysis of the system shows that 0.6 mol of oxygen are present at equilibrium. The equilibrium constant for the reaction is__________. (Nearest integer)
At 600K, 2 mol of NO are mixed with 1 mol of O2.
2NO(g) + O2(g) 2NO2(g)
The reaction occurring as above comes to equilibrium under a total pressure of 1 atm. Analysis of the system shows that 0.6 mol of oxygen are present at equilibrium. The equilibrium constant for the reaction is__________. (Nearest integer)
Initial moles2mol1 mol
At equilibrium (2 – 2x) mole (1 – x) mol2x mol
= 2 0.8 = 1.2
= 1.925
the nearest integer = 2.
When 600 mL of 0.2 M HNO3 is mixed with 400 mL of 0.1 M NaOH solution in a flask, the rise in temperature of the flask is_________ × 10-2 °C.
(Enthalpy of neutralization = 57 kJ mol-1 and Specific heat of water = 4.2 JK-1 g-1)
(Neglect heat capacity of flask)
When 600 mL of 0.2 M HNO3 is mixed with 400 mL of 0.1 M NaOH solution in a flask, the rise in temperature of the flask is_________ × 10-2 °C.
(Enthalpy of neutralization = 57 kJ mol-1 and Specific heat of water = 4.2 JK-1 g-1)
(Neglect heat capacity of flask)
HNO3 + NaOH ® NaNO3 + H2O
t = 0, (600 × 0.2)meq  
Which among the following is the strongest Bronsted base?
Which among the following is the strongest Bronsted base?
Due the absence of inversion and non resonating nature
If the equilibrium constant for is and that of is , the equilibrium constant for is:
If the equilibrium constant for is and that of is , the equilibrium constant for is:
0.001 M NaOH solution has [OH-] = 0.001 M = 10-3 M
Using ; pOH =
=
pOH = 3
pH = 14 – pOH
pH = 14 – 3
pH = 11
What effect does a catalyst have on the equilibrium position of a reaction?
(a) A catalyst favours the formation of products
(b) A catalyst favours the formation of reactants
(c) A catalyst does not change the equilibrium position of a reaction
(d) A catalyst may favour reactants or product formation, depending upon the direction in which the reaction is written.
What effect does a catalyst have on the equilibrium position of a reaction?
(a) A catalyst favours the formation of products
(b) A catalyst favours the formation of reactants
(c) A catalyst does not change the equilibrium position of a reaction
(d) A catalyst may favour reactants or product formation, depending upon the direction in which the reaction is written.
Answer: (a) A catalyst favours the formation of products
