Haloalkanes and Haloarenes

The major product (P) in the reaction

The decreasing order of reactivity of the following organic molecules towards ${\mathrm{A}\mathrm{g}\mathrm{N}\mathrm{O}}_3$ solution is:

What will be the major product of following sequence of reactions?

Assertion- Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene

Reason :−NO₂ group is a m-directing group.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion : Hydrolysis of (−)−2-bromooctane proceeds with inversion of configuration.

 Reason : This reaction proceeds through the formation of a carbocation.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion- It is difficult to replace chlorine by −OH in chlorobenzene in comparison to that in chloroethane.

Reason: Chlorine-carbon (C−Cl) bond in chlorobenzene has a partial double bond character due to resonance.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion: Aryl iodides can be prepared by reaction of arenes with iodine in the presence of an oxidising agent. 

Reason : Oxidising agent oxidises I₂ into HI.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion : In monohaloarenes, further electrophilic substitution occurs at ortho and para positions. 

Reason : Halogen atom is a ring deactivator.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. 

Reason : Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.

Assertion: tert-Butyl bromide undergoes Wurtz reaction to give 2,2,3,3-tetramethylbutane.

Reason : In the Wurtz reaction, alkyl halides react with sodium in dry ether to give hydrocarbons containing double the number of carbon atoms present in the halide.

(i) Assertion and reason both are correct and reason is correct explanation of assertion.

(ii) Assertion and reason both are wrong statements.

(iii) Assertion is correct but reason is wrong statement.

(iv) Assertion is wrong but reason is correct statement.

(v) Assertion and reason both are correct statements but reason is not correct explanation of assertion.