Thermodynamics
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Two moles of an ideal gas with are mixed with 3 moles of another ideal gas with . The value of for the mixture is:
Two moles of an ideal gas with are mixed with 3 moles of another ideal gas with . The value of for the mixture is:
Under an adiabatic process, the volume of an ideal gas gets doubled. Consequently the mean collision time between the gas molecule changes from to . If for the gas then a good estimate for is given by
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Under an adiabatic process, the volume of an ideal gas gets doubled. Consequently the mean collision time between the gas molecule changes from to . If for the gas then a good estimate for is given by
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Two ideal Carnot engines operate in cascade (all heat given up by one engine is used by the other engine to produce work) between temperatures, and . The temperature of the hot reservoir of the first engine is and the temperature of the cold reservoir of the second engine is . is temperature of the sink of first engine which is also the source for the second engine. How is related to and , if both the engines perform equal amount of work?
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Two ideal Carnot engines operate in cascade (all heat given up by one engine is used by the other engine to produce work) between temperatures, and . The temperature of the hot reservoir of the first engine is and the temperature of the cold reservoir of the second engine is . is temperature of the sink of first engine which is also the source for the second engine. How is related to and , if both the engines perform equal amount of work?
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Two Carnot engines A and B operate in series such that engine A absorbs heat at T? and rejects heat to a sink at temperature T. Engine B absorbs half of the heat rejected by Engine A and rejects heat to the sink at T?. When work done in both the cases is equal, the value of T is:
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Two Carnot engines A and B operate in series such that engine A absorbs heat at T? and rejects heat to a sink at temperature T. Engine B absorbs half of the heat rejected by Engine A and rejects heat to the sink at T?. When work done in both the cases is equal, the value of T is:
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η_A = W_A/Q? = 1 - T/T?
η_B = W_B/Q? ' = 1 - T? /T
W_A = Q? (1 - T/T? ) = Q? - Q?
W_B = Q? ' (1 - T? /T) = Q? /2 (1 - T? /T)
Given W_A = W_B
Q? (1 - T/T? ) = (Q? /2) (1 - T? /T)
Q? (T? /T) (1-T/T? ) = (Q? /2) (1-T? /T)
(T? /T - 1) = (1/2) (1-T? /T)
2T? /T - 2 = 1 - T? /T
2T? /T + T? /T = 3
T = (2T? +T? )/3
One mole of an ideal gas is taken through an adiabatic process where the temperature rises from 27°C to 37°C. If the ideal gas is composed of polyatomic molecule that has 4 vibrational modes, which of the following is true? [R = 8.314 J mol⁻¹K⁻¹]
One mole of an ideal gas is taken through an adiabatic process where the temperature rises from 27°C to 37°C. If the ideal gas is composed of polyatomic molecule that has 4 vibrational modes, which of the following is true? [R = 8.314 J mol⁻¹K⁻¹]
Degrees of freedom (f) = 3 translational + 3 rotational + (2 × 4) vibrational = 14
γ = 1 + 2/f = 1 + 2/14 = 8/7
W = nR? T/ (γ-1) = (1 × 8.3 × (310-300)/ (8/7 - 1) = (83)/ (1/7) = 581 J
As W is positive, work is done by the gas. The solution says W<0, work done on the gas. This implies? T is negative. The question states temperature rises, so work is done on the gas. W = -582J.
For water at 100°C and 1 bar, ΔᵥₐₚH - ΔᵥₐₚU = _______ × 10² J mol⁻¹ (Round off to the Nearest integer) [Use: R = 8.31 J mol⁻¹ K⁻¹] [Assume volume of H₂O(l) is much smaller than volume of H₂O(g). Assume H₂O(g) can be treated as an ideal gas]
For water at 100°C and 1 bar, ΔᵥₐₚH - ΔᵥₐₚU = _______ × 10² J mol⁻¹ (Round off to the Nearest integer) [Use: R = 8.31 J mol⁻¹ K⁻¹] [Assume volume of H₂O(l) is much smaller than volume of H₂O(g). Assume H₂O(g) can be treated as an ideal gas]
H? O (l) → H? O (g)
ΔH° = ΔU° + ΔngRT
ΔH° - ΔU° = ΔngRT
= 1 × 8.31 × 373
= 3099.63 J/mol
= 30.9963 × 10² J/mol
≈ 31 × 10² J/mol
A body takes 4 min. to cool from 61°C to 59°C. If the temperature of the surroundings is 30°C, the time taken by the body to cool from 51°C to 49°C is:
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A body takes 4 min. to cool from 61°C to 59°C. If the temperature of the surroundings is 30°C, the time taken by the body to cool from 51°C to 49°C is:
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-dT/dt = K [T - Ts]
- (61-59)/4 = K [ (61+59)/2 - 30]
-0.5 = K [60 - 30] = 30K
So, K = -1/60 min? ¹
Again - (51-49)/t = K [ (51+49)/2 - 30]
-2/t = (-1/60) [50-30] = -20/60 = -1/3
t = 6 min
In the reported figure, there is a cyclic process ABCDA on a sample of 1mol of a diatomic gas. The temperature of the gas during the process A→B and C→D are T? and T? (T? > T?) respectively. Choose the correct option out of the following for work done if processes BC and DA are adiabatic.
In the reported figure, there is a cyclic process ABCDA on a sample of 1mol of a diatomic gas. The temperature of the gas during the process A→B and C→D are T? and T? (T? > T?) respectively. Choose the correct option out of the following for work done if processes BC and DA are adiabatic.
A→B & D→C (isothermal process)
So, TA = TB & TD = TC. Now B→C & D→A (adiabatic process)
|WBC| = nR/ (γ-1) (TB - TC)
|WAD| = nR/ (γ-1) (TA - TD) = nR/ (γ-1) (TB - TC)
∴ |WBC| = |WAD|
A heat engine has an efficiency of 1/6. When the temperature of sink is reduced by 62°C, its efficiency get doubled. The temperature of the source is :
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A heat engine has an efficiency of 1/6. When the temperature of sink is reduced by 62°C, its efficiency get doubled. The temperature of the source is :
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η = 1 - T? /T?
1/6 = 1 - T? /T? (i)
2η = 1/3 = 1 - (T? -62)/T? (ii)
By (i) and (ii)
(T? /T? ) = 5/6
1/3 = 1 - (T? /T? ) + 62/T? = 1 - 5/6 + 62/T?
1/3 = 1/6 + 62/T?
1/6 = 62/T?
T? = 62 × 6 = 372K = 99°C
n mole of perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A->B : Isothermal expansion at temperature T so that the volume is doubled from V1 to V2 and Pressure changes from P1 to P2.
B->C : Isobaric compression at pressure P2 to initial volume V1.
C->A : Isobaric change leading to change of pressure from P2 to P1.
Total work done in the complete cycle ABCA is:
n mole of perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A->B : Isothermal expansion at temperature T so that the volume is doubled from V1 to V2 and Pressure changes from P1 to P2.
B->C : Isobaric compression at pressure P2 to initial volume V1.
C->A : Isobaric change leading to change of pressure from P2 to P1.
Total work done in the complete cycle ABCA is:
[At B, 2P2 V1 = nRT]


