Thermodynamics

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New answer posted•a year ago
S
a year ago

  γ mixture   = n 1 C P 1 + n 2 C P 2 n 1 C V 1 + n 2 C V 2 = n 1 γ 1 R γ 1 - 1 + n 2 γ 2 R γ 2 - 1 n 1 R γ 1 - 1 + n 2 R γ 2 - 1

on rearranging we get

n 1 + n 2 γ mix   - 1 = n 1 γ 1 - 1 + n 2 γ 2 - 1 ; 5 γ mix   - 1 = 3 1 / 3 + 2 2 / 3

5 γ mix   - 1 = 9 + 3 = 12 ⇒ γ mixture   = 17 12 + 1 + 5 12 ; γ mix   = 1.42

 

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New answer posted•a year ago
New answer posted•a year ago
New answer posted•a year ago
S
a year ago

η_A = W_A/Q? = 1 - T/T?
η_B = W_B/Q? ' = 1 - T? /T
W_A = Q? (1 - T/T? ) = Q? - Q?
W_B = Q? ' (1 - T? /T) = Q? /2 (1 - T? /T)
Given W_A = W_B
Q? (1 - T/T? ) = (Q? /2) (1 - T? /T)
Q? (T? /T) (1-T/T? ) = (Q? /2) (1-T? /T)
(T? /T - 1) = (1/2) (1-T? /T)
2T? /T - 2 = 1 - T? /T
2T? /T + T? /T = 3
T = (2T? +T? )/3

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New answer posted•a year ago
S
a year ago

Degrees of freedom (f) = 3 translational + 3 rotational + (2 × 4) vibrational = 14
γ = 1 + 2/f = 1 + 2/14 = 8/7
W = nR? T/ (γ-1) = (1 × 8.3 × (310-300)/ (8/7 - 1) = (83)/ (1/7) = 581 J
As W is positive, work is done by the gas. The solution says W<0, work done on the gas. This implies? T is negative. The question states temperature rises, so work is done on the gas. W = -582J.

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New answer posted•a year ago
New answer posted•a year ago
S
a year ago

-dT/dt = K [T - Ts]

  • (61-59)/4 = K [ (61+59)/2 - 30]
    -0.5 = K [60 - 30] = 30K
    So, K = -1/60 min? ¹
    Again
  • (51-49)/t = K [ (51+49)/2 - 30]
    -2/t = (-1/60) [50-30] = -20/60 = -1/3
    t = 6 min

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New answer posted•a year ago
S
a year ago

A→B & D→C (isothermal process)
So, TA = TB & TD = TC. Now B→C & D→A (adiabatic process)
|WBC| = nR/ (γ-1) (TB - TC)
|WAD| = nR/ (γ-1) (TA - TD) = nR/ (γ-1) (TB - TC)
∴ |WBC| = |WAD|

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New answer posted•a year ago
S
a year ago

η = 1 - T? /T?
1/6 = 1 - T? /T? (i)
2η = 1/3 = 1 - (T? -62)/T? (ii)
By (i) and (ii)
(T? /T? ) = 5/6
1/3 = 1 - (T? /T? ) + 62/T? = 1 - 5/6 + 62/T?
1/3 = 1/6 + 62/T?
1/6 = 62/T?
T? = 62 × 6 = 372K = 99°C

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New answer posted•a year ago
S
a year ago

  W A B = n R T l n 2 V 1 V 1 = n R T l n 2 .       

  W B C = P 2 ( V 1 − 2 V 1 ) = − P 2 V 1 = − 1 2 n R T          

[At B, 2P2 V1 = nRT]

W C A = 0           [CA is isochoric process].

W A B C A = W A B + W B C + W C A = n R T ( l n ( 2 ) − 1 2 )            

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