Aldehydes, Ketones and Carboxylic Acids

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New answer posted

2 months ago

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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Payal Gupta

Contributor-Level 10

P 4 + 3 N a O H + 3 H 2 O P H 3 + 3 N a H 2 P O 2

R e d P + a l k a l i H 4 P 2 O 6 ( N o P H b o n d )

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A
alok kumar singh

Contributor-Level 10

It is an uncleophilic acyl substilution. While electron withdrawing group in carboxylic acid will increases the rate of esterification.

 

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Payal Gupta

Contributor-Level 10

Consider the following image

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alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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Vishal Baghel

Contributor-Level 10

Solvent polarity is related to Rf value of nitro compounds

100 mg P-nitrophenol and picric acid have different Rf value on silica gel plate.

Preparative TLC is best to separate 100 mg of P-nitro phenol and picric acid.

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alok kumar singh

Contributor-Level 10

Correct order of priority is

SO3H>COCl>CONH2>CN

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Payal Gupta

Contributor-Level 10

Consider the following image

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Payal Gupta

Contributor-Level 10

In thin layer chromatography, the spots of colourless compounds, which are invisible to eyes can be detected by putting the plate under UV light.

Another detection technique is to place the plate in a covered jar containing I2 (s). Sometimes an appropriate reagent may also be sprayed on the plate, ninhydrin in case of amino acids

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