Chemistry

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New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

Cr2O72+2OH2CrO42+H2O

Dichromate ion converted to chromate ion in basic medium and oxidation number of Cr in CrO42 is +6.

New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

AB2 (g)? A (g)+2B (g)

Initial1 mole -

At equilirbium 1-x mole x mole2x mole

V = 25 L and

T = 300 K.

At equilibrium, P = 1.9 atm

Total moles at equilibrium, n = 1 + 2x

V = 25 L

T = 300 K

Using, PV = nRT

1.9 * 25 = (1 + 2x) * 0.08206 * 300

x = 0.465

Now;Partial pressure of AB2 at equilibrium = 0.5351.93*1.9atm

Using ; Kp=PA.PB2PAB2

Kp= (0.465*1.91.93) (2*0.4651.93*1.9)20.5351.93*1.9 = 0.728

KP = 0.73

Kp = 73 * 10-2

So; x = 73

New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

X → Y

EafEab=2030Eab=20

Eab=50kJ/mole

New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

MnO4+8H+5eMn+4H2OEo=1.51V

Quantity of electricity required to reduce 1 mole of MnO4 is 5F

So, for 5 mole MnO4 25F electricity is required.

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Payal Gupta

Contributor-Level 10

P (Vmb)=RT

PVmRTPbRT=1

Z=1+PbRT

(zP)T=bRT

So, comparing with xbRT

x = 1

New answer posted

4 months ago

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Payal Gupta

Contributor-Level 10

[Mn2 (CO)10]

Bridging ligand (CO) is (0)

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Payal Gupta

Contributor-Level 10

This is free radical mechanism, bromination takes place at benzylic carbon (major product).

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Payal Gupta

Contributor-Level 10

Heavy water (D2O) is used in organic reaction to know the kinetics of reaction

Heavy water D2O is obtained by repeated electrolysis of H2O.

Heavy water has b.pt 101.4°C and ordinary water has b.pt 100°C

(b.pt of D2O > b.pt of H2O)

D2O has more molecular mass than H2O, so greater degree of association and hence greater b.pt and viscosity.

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Payal Gupta

Contributor-Level 10

O3 generally exist in stratosphere and they acts as protector, because it protect us from harmful UV radiations but sometimes O3 formed in troposphere and it acts as a pollutants.

O3 in stratosphere : - Protector

O3 in Troposphere : - Pollutant (photochemical smog)

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4 months ago

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Payal Gupta

Contributor-Level 10

o - Nitrophenol is more volatile due to intramolecular hydrogen bonding,

So I statement is correct but statement (II) is false

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