Chemistry

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New answer posted

4 months ago

0 Follower 6 Views

R
Raj Pandey

Contributor-Level 9

ΔH? = ΔH? + ΔH?
= 2.8 + 98.2 = 101 kJ/mole

New answer posted

4 months ago

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R
Raj Pandey

Contributor-Level 9

Number of sigma bonds are 10.
[Structure showing 10 sigma bonds in the molecule]

 

New answer posted

4 months ago

0 Follower 4 Views

R
Raj Pandey

Contributor-Level 9

Solubility of 2 group hydroxide increases down the group.


New answer posted

4 months ago

0 Follower 19 Views

R
Raj Pandey

Contributor-Level 9

[Reactions showing reduction of various functional groups]
(1) Nitrile reduced to primary amine with H? /Ni.
(2) Nitrile and aldehyde reduced to primary amine and alcohol with LAH.
(3) Nitro group reduced to primary amine with Na/Hg, C? H? OH.
(4) Nitrile reduced to aldehyde with SnCl? /HCl.
Products of reaction 1, 2 and 3 are 1° amines, so react with Hinsberg's reagent to form sulphonamide. Product of (4) is an aldehyde, which does not react.

New answer posted

4 months ago

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R
Raj Pandey

Contributor-Level 9

Cl?C=CCl? is not used for dry cleaning of clothes due to safety purpose.

New answer posted

4 months ago

0 Follower 5 Views

V
Vishal Baghel

Contributor-Level 10

H? O (l) → H? O (g)
ΔH° = ΔU° + ΔngRT
ΔH° - ΔU° = ΔngRT
= 1 * 8.31 * 373
= 3099.63 J/mol
= 30.9963 * 10² J/mol
≈ 31 * 10² J/mol

New answer posted

4 months ago

0 Follower 8 Views

V
Vishal Baghel

Contributor-Level 10

Let volume of solution = x ml
So mass of solution = 1.2x
And mass of water = x gm
Mass of solute = 0.2x
Molality = (W_solute * 1000) / (M_solute * W_solvent) = (0.2x * 1000) / (40 * x) = 5 m

New answer posted

4 months ago

0 Follower 12 Views

R
Raj Pandey

Contributor-Level 9

(a) Rate vs Time for zero order is a horizontal line (Rate = const.)
(b) t?/? vs Concentration for zero order is a straight line through the origin (t?/? ∝ [C?])
(c) Concentration vs Time for first order is an exponential decay (C? = C?e?)
(d) Concentration vs Time for a reaction is a decreasing curve, not a horizontal line.
(e) Rate vs Concentration for first order is a straight line through the origin (Rate = k[Conc.]¹)

New answer posted

4 months ago

0 Follower 3 Views

V
Vishal Baghel

Contributor-Level 10

B.O. of CO = 3
B.O. of NO? = 3
Both are isoelectronic
So difference = 0
∴ x = 0

New answer posted

4 months ago

0 Follower 12 Views

V
Vishal Baghel

Contributor-Level 10

PCl? (g)? PCl? (g) + Cl? (g); Kc = 1.844
t=0: 3, 0, 0
equilibrium: 3-x, x
Kc = x² / (3-x) = 1.844
x² + 1.844x - 5.532 = 0
x = (-1.844 + √ (1.844² - 4 (1) (-5.532)/2 = (-1.844 + √25.528)/2 ≈ 1.604
At equilibrium number of moles of PCl? = (3 - 1.604) = 1.396 mol
= 1396 * 10? ³ mol

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