Chemistry

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alok kumar singh

Contributor-Level 10

Co (NH? )? ] [Cr (CN)? ]: Co-ordination isomerism

[Co (NH? )? (NO? )? ]: Linkage isomerism

[Cr (H? O)? ]Cl? : Solvate isomerism

Cis- [CrCl? (Ox)? ]³? : Optical isomerism

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Raj Pandey

Contributor-Level 9

Please consider the following Image

 

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alok kumar singh

Contributor-Level 10

CN? and NO? are examples of ambident nucleophiles.

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alok kumar singh

Contributor-Level 10

The change in entropy for the following processes is negative (ΔS = -ve), indicating an increase in order:

Water (l) → Ice (s) at 0°C

H? O (l) → Ice (s) at -10°C

N? (g) + 3H? (g) → 2NH? (g)

Adsorption

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alok kumar singh

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The reaction shown is:
Anisole diazonium chloride (A) + Ethanol → Anisole + Acetaldehyde (X) + HCl + N? (Y)

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Raj Pandey

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Please consider the following Image

 

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alok kumar singh

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The reactions in the Solvay process are:

NaCl + H? O + NH? + CO? → NH? Cl + NaHCO?

2NaHCO? → Na? CO? + CO? + H? O

2NH? Cl + Ca (OH)? → CaCl? + 2NH? + H? O

CaCl? is a byproduct of the process.

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Raj Pandey

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o   Chlorophyll: Magnesium present in chlorophyll.

o   Vitamin B? : Cobalt (cyanocobalamin).

o   Anticancer drug: Platinum (Coordination compound of platinum).

o   Grubbs catalyst: Ruthenium.

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alok kumar singh

Contributor-Level 10

The addition of HBr to H? C−CH? −CH=CH? proceeds via carbocation formation.

Formation of a 1° Carbocation (A): H? C−CH?

Formation of a 2° Carbocation (B): H? C−CH? −C? H−CH?

The 2° carbocation (B) is more stable than the 1° carbocation (A). Therefore, the activation energy (Ea) for the formation of B is lower, and B is formed faster.

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Raj Pandey

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o   Alcoholic potassium hydroxide (Alc KOH):- used for β - elimination.

o   Pd / BaSO? : - Lindlar's Catalyst.

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