Chemistry

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New answer posted

9 months ago

0 Follower 5 Views

A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

New answer posted

9 months ago

0 Follower 2 Views

R
Raj Pandey

Contributor-Level 9

Solubility of CdSO? is water ; S = 8 * 10? M
Using Ksp = S²
Ksp = 64 * 10? M
Now,
CdSO? Cd²? + SO? ²?
in H? SO? (0.01M)
Ksp = [Cd²? ] [SO? ²? ]
64 * 10? = S? (S? + 0.01)
S? << 0.01
So, S? = 64 * 10? M.

New answer posted

9 months ago

0 Follower 21 Views

R
Raj Pandey

Contributor-Level 9

ΔG° = + 25.2 kJ / mol
Using ΔG° = -2.3 RT log Kp
25.2 * 10³ = - 2.3 * 8.3 * 400 log Kp

o   3.3 = log Kp
log (1 / 2*10³) = log Kp
Kp = 1 / (2*10³)
Using; Kp = Kc (RT)
1 / (2*10³) = Kc (0.083 * 400)? ¹

New answer posted

9 months ago

0 Follower 4 Views

R
Raj Pandey

Contributor-Level 9

Moles of benzoic acid = 6.1 / 121 = 0.05
Theoretical moles of m- bromobenzoic acid = 0.05
Observed moles of m- bromobenzoic acid = 7.8 / 200 = 0.039
% yield = (0.039 / 0.05) * 100 = 78%

New answer posted

9 months ago

0 Follower 2 Views

R
Raj Pandey

Contributor-Level 9

Half life, t? /? = 1min
Let, time of 99.9% completion of reaction be 't' min
Let the reaction is of first order
K = (2.303/t) log? ( [R]? / [R])
[R] = 0.001 [R]?
t = (2.303 * 3 min) / 0.693
t = 9.99 min
the nearest integer is 10.

New answer posted

9 months ago

0 Follower 8 Views

A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

New answer posted

9 months ago

0 Follower 3 Views

R
Raj Pandey

Contributor-Level 9

λ° (BaCl? ) = 280 Scm²mol? ¹
λ° (H? SO? ) = 860 Scm²mol? ¹
λ° (HCl) = 426 Scm²mol? ¹
λ° (BaSO? ) = λ° (BaCl? ) + λ° (H? SO? ) - 2λ° (HCl)
= 280 + 860 - 2 * 426
= 288 Scm² mol? ¹

New answer posted

9 months ago

0 Follower 2 Views

A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

New answer posted

9 months ago

0 Follower 2 Views

R
Raj Pandey

Contributor-Level 9

V (Na? CO? ) = 10 mL
Volume of HCl used will be 5 mL (average of titre values)
Meq of HCl = meq of Na? CO?
(M * n-factor * V)HCl = (M * n-factor * V)Na? CO?
0.2 * 1 * 5 = M * 2*10
M= 0.05 M
M= 50 mM

New answer posted

9 months ago

0 Follower 5 Views

R
Raj Pandey

Contributor-Level 9

In Tollen's test for aldehyde, aldehyde is oxidized to carboxylic acid salt as:
R – CHO + H? O →R – COO? + 3H? + 2e?
So; 2e? are transferred per aldhyde group.

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