The S Block Elements

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Vishal Baghel

Contributor-Level 10

(i) Lattice energy of BeO is comparatively higher than the hydration energy. Therefore, it is almost insoluble in water. Whereas, BeSO4 is ionic in nature and its hydration energy dominates the lattice energy.

(ii) Both BaO and BaSOare ionic compounds but the hydration energy of BaO is higher than the lattice energy therefore it is soluble in water.

(iii) Since the size of Li+ ion is very small in comparison to K+ ion, it polarises the electron cloud of I ion to a great extent. Thus, Lil dissolves in ethanol more easily than the KI.

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Vishal Baghel

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(a) Na2O2 + 2H2O → 2NaOH + H2O2

(b) 2KO2 + 2H2O → 2KOH + O2+ H2O2

(c) Na2O+ CO2 → Na2CO3

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Vishal Baghel

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(a) Na2CO3 is a salt of a weak acid, carbonic acid (H2CO3) and a strong base NaOH. Thus, it undergoes hydrolysis to produce strong base NaOH and its aqueous solution isalkaline in nature.
Na2CO3 (s) + H2O (l) → 2NaOH

(b) Because the discharge potential of alkali metals is much higher than that of hydrogen, therefore when the aqueous solution of any alkali metal chloride is subjected to electrolysis, H2, instead of the alkali metal, is produced at the cathode. Therefore, alkali metals are prepared by electrolysis of their fused chlorides.

(c) Since potassium is move reactive than sodium and it is found in nature to a less extent

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Vishal Baghel

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(a) Smaller the size of the ion, more highly it is hydrated and hence greater is the mass of the hydrated ion and thus the ionic mobility become lesser. The extent of hydration decreases in the order.
Li+ < Na+ + < Rb+ < Cs+
Thus the mobility of Cs+ will be the highest

(b) Due to its smaller size lithium can form nitride directly as an exceptional behaviour unlike other alkali metals.

(c) It is because reduction potential depends upon sublimation energy, ionisation energy and hydration energy. Their resultant is almost constant for these ions.

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Vishal Baghel

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(i) 2Na + 2H2O → 2NaOH + H2
(ii) 2Na + O2 → Na2O2
(iii) Na2O2 + 2H20 → 2NaOH + H2O2

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Vishal Baghel

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Sodium:

  • Na+ions participate in the transmission of nerve signals, in regulating the flow of water across cell membranes.
  • In the transport of sugars and amino acids into cell.

Potassium:

  • K+ions activate many enzymes.
  • Participate in the oxidation of glucose to produce ATP.

Magnesium:

  • All enzymes that utilise ATP in phosphate transfer require magnesium as a cofactor.
  • Mg is the central metal ion present in chlorophyll pigment in plants.

Calcium:

  • Ca2+ ions are present in bones.
  • plays important roles in neuromuscular function.

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Vishal Baghel

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It is due to high lattice energy of LiF as compared to LiCl.
LiCl is soluble in water because its hydration energy is higher than its lattice energy.

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Vishal Baghel

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Li+ can polarize water molecules easily than the other alkali metal ions because of its small size.

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Vishal Baghel

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Limestone:

  • A raw material for cement.
  • It is used as a building material in the form ofmarble and in the manufacture of quick lime.
  • used in the manufactureof high quality paper. It is also used as anantacid, mildabrasive in tooth paste, aconstituent of chewing gum, and a filler incosmetics.

Cement:

  • It is used in concrete and reinforcedconcrete, in plastering and in the construction
  • of bridges, dams and buildings

Plaster of Paris:

  • It is used in the building industry as well as plasters.
  • It is usedfor immobilising the affected part of organ wherethere is a bone fracture or sprain.
  • It is alsoemployed in dentistry, in ornamental work andfor making ca
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Vishal Baghel

Contributor-Level 10

Since group 1 hydroxides and carbonates due to large size contain higher hydration energy than the lattice energy so, they are easily soluble in water. Whereas, in magnesium and calcium due to small size their lattice energy dominates over hydration energy they are sparingly soluble in water.

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