Alcohol Phenol And Ethers

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R
Raj Pandey

Contributor-Level 9

[Reaction of an α, β-unsaturated ketone with ethyl magnesium bromide (Grignard reagent) followed by hydrolysis to give a tertiary alcohol via 1,2-addition.]

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V
Vishal Baghel

Contributor-Level 10

Kindly consider the following figure

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A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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Payal Gupta

Contributor-Level 10

o - Nitrophenol is more volatile due to intramolecular hydrogen bonding,

So I statement is correct but statement (II) is false

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alok kumar singh

Contributor-Level 10

First reaction is EAS which will be given by that phenol derivative whose p-position is free for EAS reaction.

 

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Vishal Baghel

Contributor-Level 10

Ceric ammonium nitrate is used to test alcohol while CHCl3/alc. KOH is used to test 1° amine

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A
alok kumar singh

Contributor-Level 10

Kindly go through the solution

 

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Payal Gupta

Contributor-Level 10

Acidic order

Simple concept of conjugate base stability.

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alok kumar singh

Contributor-Level 10

Compound A is phenol since phenol gives dark green colour with FeCl3.

 

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alok kumar singh

Contributor-Level 10

Esters on treating with excess CH3MgBr followed by hydrolysis gives 3° alcohol.

 

 

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