Aldehydes, Ketones and Carboxylic Acids

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V
Vishal Baghel

Contributor-Level 10

Reduction of alkyl cyanide using SnCl2 and HCl is called as Stephen reduction reaction.

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R
Raj Pandey

Contributor-Level 9

D and E are non-resolvable.

D = P h - C H 2 - C H 2 - C H 3 ? H + / K M n O 4 P h - C O O H   (Benzoic Acid)

Or 

 

 

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Raj Pandey

Contributor-Level 9

Nucleophilic addition on carbonyl compounds decreases by increasing steric hindrance.

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alok kumar singh

Contributor-Level 10

Process of active methylene group  acidic strength and the side chain should be e- withdrawing.

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Vishal Baghel

Contributor-Level 10

If the carbonyl compound is sterically crowded, then it will be reluctant to undergo addition reaction. Moreover, attachment of bulkier alkyl group with the carbonyl carbon decreases the partial positive charge resulting into the minimization of attack by R? from RMgBr. So, the order is

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Raj Pandey

Contributor-Level 9

Kindly consider the following Image 

 

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V
Vishal Baghel

Contributor-Level 10

Here cyclohexanone is formed as follows

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