
In dynamic equilibrium, the rate of reaction in the forward and reverse is the same. This delicate balance is affected by many external factors. Le Chatelier's Principle states that if the system at equilibrium is disturbed, then it will adjust itself in such a way that it reduces or counteracts the effect of the change.
Chemical equilibrium can be affected due to key factors such as temperature, pressure, concentration and presence of a catalyst. Knowledge of factors affecting the equilibrium is important to master industrial processes like the Haber process. Also, you can surpass in the board exams and competitive tests like JEE and NEET. Check the article and know in detail about the factors affecting equilibria.
- What is Chemical Equilibrium?
- Types of Equilibrium
- Factors Affecting Chemical Equilibria
What is Chemical Equilibrium?
Chemical Equilibrium is a state where the rate of forward and backwards reactions is equal. This is applicable in a reversible chemical reaction. At this point, the concentration of products and reactants is constant over time.
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Key Feature of Chemical Equilibrium
- Occurs in reversible reactions
- The system seems to be at rest, but it is in dynamic equilibrium ( reactions still proceed).
- Concentration, temperature, and pressure are the factors that affect the equilibrium.
- Chemical equilibrium is expressed in the equilibrium constant (Kc or Kp).
Types of Equilibrium
Equilibrium is of various types based on the physical state of the reactants and products involved in reactions. The main types of equilibrium are:
- Homogeneous Equilibria: It is a state in a chemical reaction where all reactants and products are in the same phase, typically gaseous or aqueous.
- Heterogeneous Equilibria: A state in a chemical reaction with more than one phase is called a heterogeneous equilibrium. For example, the equilibrium between water vapour and liquid water in a closed container.
- Physical Equilibrium: It is a state where no chemical reaction is involved. Only physical changes like boiling, dissolving and melting.
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Factors Affecting Chemical Equilibria
Various external factors affect the position of a chemical equilibrium. The concentration of products and reactants in a reversible reaction is affected by these changes. The major factors affecting the equilibria are mentioned below:
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Major Factors Affecting Equilibrium.
- Change in Concentration: Addition or removal of products or reactions moves the equilibrium to restore balance. Examples: when the reactant concentration increases moves the equilibrium to the right.
- Temperature: The effect of temperature is based on whether the reaction is endothermic or exothermic. Example: an exothermic reaction increases in temperature shifts the equilibrium to the left, and in an endothermic reaction, it shifts to the right.
- Pressure (for gaseous system only): The equilibrium position is affected on both sides when the number of moles of gas is different on both sides.
Chemistry Chemical Equilibrium Exam
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Other Topics under this Chapter
- Chemical Equilibrium
- Lewis Acids and Bases
- Precipitation Titration
- Arrhenius Acid
- Hydrocyanic Acid
- Equilibrium Processes
- Equilibrium in Chemical Processes
- Homogeneous Equilibria
- Heter Heterogeneous Equilibria
- Applications of Equilibrium Constant
- Factors Affecting Equilibria
- Ionic Equilibrium in Solution
- Acids, Bases and Salts
- Ionization of Acids and Bases
- Solubility Equilibria of Sparingly Soluble Salts
Other Class 11th Chemistry Chapters
- Chemistry Chemical Equilibrium
- Chemistry Structure of Atom
- Chemistry Redox Reactions
- Chemistry Some Basic Concepts of Chemistry
- Chemistry Organic Chemistry
- NCERT Class 11 Chemistry
- Chemistry Classification of Elements and Periodicity in Properties
- Chemistry Chemical Bonding and Molecular Structure
- Chemistry Hydrocarbon
- Chemistry Thermodynamics
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